Emulsion Polymerization Of Vinyl Chloride
Emulsion polymerization has several advantages over other polymerization techniques.
Emulsion polymerization of vinyl chloride. Berens corporate research the b. These primary particles then may simply grow by conversion of monomer to polymer within these particles or undergo aggrega. The reacting mixture is stirred by a multipaddle agitator which is connected to a constant velocity motor 200 rpm. Polyvinyl acetate is synthesized by the emulsion polymerisation of vinyl acetate monomer vam.
Figure 1 shows a scheme of the reaction system employed. Suspension polymerization of vinyl chloride in a stirred reactor 385. Effects of polymerization variables on the properties of vinyl acetate based emulsion polymers by hale berber yamak submitted. For batch emulsion polymerization of vinyl chloride vcm.
Emulsion polymerization accounts for about 12 and bulk polymerization accounts for 8. Bottle suspension polymerization of vinyl chloride 382. Suspension polymerization affords particles with average diameters of 100 180 μm whereas emulsion polymerization gives much smaller particles of average size around 0 2 μm. γ ray induced emulsion polymerization of vinyl chloride γ ray induced emulsion polymerization of vinyl chloride wang ung ping 1962 09 01 00 00 00 y ray induced emulsion polymerization of vinyl chloride ung ping wang 32 emulsion polymerization of vinyl chjoride induced by lay irr adiation has been studied the effects of irradiation time of emulsifier concentration of vinyl.
Pvac emulsions are best known for their use in wood glues or school glues due to their strong adhesion properties. November 10th 2011 reviewed. The stirring system is. Pvc forms as tiny particles which grow and when they reach a desired size the reaction is stopped and any unreacted vinyl chloride is distilled off and re used.
Journal of applied polymer science vol. Vinyl acetate homopolymer pva polyvinyl acetate homopolymer emulsions often called pvac or occasionally pva homopolymers. July 11th 2012 published. Suspension polymerization of.
The role of water is to remove and control the heat given off in the polymerization process. 2379 2390 1974 continuous emulsion polymerization of vinyl chloride a. Suspension polymerization of vinyl chloride with a mixture of a suspending agent and a surfactant 385. Suspension polymerization of vinyl chloride in sealed tubes 383.